(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
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(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) cid-free paper.HeadquartersMarcel Dekker. Inc.270 Madison Avenue, New York. NY 10016tel: 212-696-9000: fax: 212-685-4540Eastern Hemisphere DistributionMarcel Dekker AGHutgasse 4. Postfach 812. CH-4001 Basel. Switzerlandtel: 41-61-261-8482; fax: 41-61-261-8896World Wide Webhttp://www.dckker.coinThe p (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) ublisher offers discounts on this book when ordered in bulk quantities. For more information, write to Special Sales/Professional Marketing at the hea(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
dquarters address above.Copyright © 2001 by Marcel Dekker. Inc. All Rights Reserved.Neither this book nor any part may be reproduced or transmitted in://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) system, without permission in writing from the publisher.Current priming (last digit):10 9 8 7 6 5 4 3 2 1PrefacePolyelectrolytes are polymers bearing dissociated ionic groups. Their unique properties, dominated by strong long-range electrostatic interactions, have been studied over the past few dec (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) ades. Substantial theoretical and experimental efforts have been made, for example, to understand the origin of “slow" domains or “loose" clusters in(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
semidilute solutions of highly charged polyelectrolytes. This kind of attractive interaction between macroions is not consistent with the standard the://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) ing of their counterions or attraction by expansion of the condensed layers between charged rods have been suggested to explain the appearance of these formations. Particular focus has also been placed on poly ion interactions with counterions, since their condensation on the polyion surface is one (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) of the most characteristic properties of the polyclcctrolytcs. The interaction of polyions with other charged or neutral species and. in particular, t(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
he adsorption of ionizable polymers al interfaces, is the second aspect of the physical chemistry of polyeleclrolytes that has been extensively studie://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) nvestigations has increased in the last fewyears as evidenced by the first two International Symposiums on Polyelectrolytes, held in 1995 and 1998. The number of papers dealing with polyelectrolytes has also increased substantially. This is not surprising consid-ivPrefacepaper making, mineral separa (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) tion, paint and food industries, cosmetics and pharmacy, water treatment processes, and soil remediation. The fabrication of layer-by-layer assembled(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
multicomposite films, which fall in a category of novel nanomaterials, presently hold a central place in this area.The purpose of this volume is to co://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) h efforts toward solving many problems in this interdisciplinary field. Practical utilization of these results is beyond doubt. The book is addressed to scientists working in the fields of biochemistry. molecular biology, physical chemistry of colloids and ionizable polymers, and their applications (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) in related technical processes.The volume consists of three parts. The first deals with static and dynamic properties of salt-free polyelectrolyte sol(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
utions and of solutions with added salts. An extension is presented of the counterion condensation theory to the calculation of counterion-polyion. co://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) lutions of polyelectrolytes. The origin of counterion-mediated attraction between like-charged chains is also discussed within a charge fluctuation approach that reconciles the thermal fluctuation approach with the ionic crystal one. A new criterion for counterion condensation is introduced through (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) molecular dynamics simulations of a cell-like model for stiff polyelectrolytes; the effects considered include polyions overcharging, charge oscillati(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
ons, and attractive interactions. Metropolis Monte Carlo simulation is also applied to calculate counterion distributions, electric potentials, and fl://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) lectrolyte molecules are treated in two limiting situations—for a single macromolecule at infinite dilution and for a polyelectrolyte gel. Although emphasis is placed on the recent developments in the theory of polyelectrolytes, this first part provides a partial review of the new experimental resul (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) ts that try to explain different aspects of the physical chemistry of polyelectrolytes.The second part is devoted to adsorption of polyelectrolytes at(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
interfaces and to flocculation and stabilization of particles in adsorbing polymer solutions. A recent theory of the electrostatic adsorption barrier://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) this part. In the following chapters, results are collected on the electrical and hydrodynamic properties of colloid-polyelectrolyte surface layers, giving information on the structure of adsorbed layers and their influence on the interactions between colloidal particles; examples and mechanisms are (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) analyzed of poly-PrefaceVself-assembled monolayers from synthetic polyelectrolytes on water or solid surfaces and the role of amphiphilic polyelectro(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
lytes for the emulsion stability are considered. Special attention is given to surface force measurements that show how association between polyelectr://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) olyte complex formation and complex-ation of polyelectrolytes with surfactants and proteins. Mobility of short chains and dynamic properties of polyelectrolyte gels are also considered. Phase transitions in ionic gels are explained with simple models in which polymer-polymer interactions are taken i (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) nto account at a molecular level. In the second chapter of this part, recent experimental and theoretical advances are summarized for gel electrophore(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
sis, which is invaluable in predicting conformation and structural changes of biologically significant macromolecules. In the following chapters, resu://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) ctric charge of the partners in the protein binding to amphiphilic polyelectrolytes: and for the micellar-like aggregation of surfactants bound to oppositely charged polyelectrolytes.I wish to thank first Professor Arthur Hubbard, who invited me to edit a volume on this rapidly expanding field. Ackn (Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001) owledgments are due to all authors for their valuable contributions and willing cooperation. I acknowledge with gratitude the assistance of Ani Peshev(Surfactant science series 99) tsetska radeva physical chemistry of polyelectrolytes marcel dekker (2001)
a in the correspondence, as well as the efforts of our production editor. Paige Force, and of all my friends who contributed to the production of this://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on ac://khothuvien.comsurfactant sciencevolumePHYSICAL CHEMISTRY OF POLYELECTROLYTESed i ted by Tsetska RadevaISBN: 0-8247-0463-0This book is printed on acGọi ngay
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