(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
➤ Gửi thông báo lỗi ⚠️ Báo cáo tài liệu vi phạmNội dung chi tiết: (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
PrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthan (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) num itself) have several unique characteristics compared to other elements, their appearance in the history of the development of organometallic chemistry is rather recent. Since the f orbitals are filled gradually from lanthanum ((Xe]4fc) to lutetium ((Xe]4f14), they are regarded as the f-block ele (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) ments, which are discriminated from the d-block transition elements.This book was edited as the second volume of “Topics in Organometallic Chemistry”,(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
aiming at an overview of recent advances of chemistry and organic synthesis of lanthanides. Since scandium (Sc) and yttrium (Y) (which lie above the PrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthan (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) stry and organic synthesis of lanthanides have developed rapidly as one of the most exciting areas. An international team of authors has been brought together in order to provide a timely and concise review of current research efforts such as lanthanide catalysis in small molecule organic synthesis (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) especially focused on carbon-carbon bond-forming reactions, chemistry and organic synthesis using low-valent lanthanides such as diiodosamarium, asymm(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
etric catalysis, lantha-nide-catalyzed polymer synthesis, and polymer-supported lanthanide catalysts used in organic synthesis. Principles of organolaPrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthan (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) nder, J. L. Namy, M. Shibasaki, Y. Waka-tsuki, and H. Yasuda for participating in this volume. J. Richmond, J. Sterritt-Brunner, and B. Benner (Springer) are also acknowledged for encouraging me to organize this work.Finally, I hope that this volume is helpful to many researchers and students who ar (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) e or will be involved in or interested in this truly exciting and hot field.Tokyo, December 1998Shu KobayashiPrinciples in Organolanthanide ChemistryR(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
einer AnwanderAnorganisch-chemisches Institut, Technische University MUnchen, Lichten-bergstrafle 4, D-85747 Garching, Germanye-mui/.-reiner.anwanderCPrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthan (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) alysis. This article outlines both the basic and advanced principles of their organometallic chemistry. The intrinsic electronic features of this 17-clcmcnt series arc reviewed in order to better understand the structural chemistry of their complexes and the resulting structure-activity relationship (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) s. Particular emphasis is placed on synthetic aspects,i.e. optimization of established procedures and alternative methods with better access to cataly(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
tically relevant species. Accordingly, tailor-made ancillary ligands are reported in detail and (he reactivity pattern of lanthanide compounds is exaPrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthan (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) ............................................. 32Intrinsic Properties of the Lanthanide Elements ................ 42.1Electronic Features............................................. 42.2Steric Features ................................................ 73Synthesis of Organolanthanide Compounds........ (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) ................. 83.1Thermodynamic and Kinetic Guidelines............................ 93.2Inorganic Reagents.........................................(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
.... 103.3Metalorganic Reagents.......................................... 153.4Thermal Stability.............................................. 234LigaPrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthan (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) s.............................................. 274.3Immobilization - “Supported Ligands”........................... 31www.pdfgrip.com5Reactivity Pattern of Organolanthanide Complexes............. 325.1Donor-Acceptor Interactions.................................. 325.2Complex Agglomerization........ (Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999) .............................. 375.3Ligand Exchange and Redistribution Reactions................. 395.4Insertion Reactions............................(Topics in organometallic chemistry vol 2) shu kobayashi lanthanides chemistry and use in organic synthesis springer (1999)
.............. 415.5Elimination Reactions- Ligand Degradation.................... 425.6Redox chemistry........................5.7Reaction Sequences - PrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthanPrefaceWhile the lanthanides (strictly defined as the 14 elements following lanthanum in the periodic table, but as normally used also include lanthanGọi ngay
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