Apparent Alkyl Transfer and Phenazine Formation via an Aryne Inte
➤ Gửi thông báo lỗi ⚠️ Báo cáo tài liệu vi phạmNội dung chi tiết: Apparent Alkyl Transfer and Phenazine Formation via an Aryne Inte
Apparent Alkyl Transfer and Phenazine Formation via an Aryne Inte
LOYOLAffl eCOMMONSLoyola University ChicagoLoyola eCommonsChemistry: Faculty Publications and other WorksFaculty Publications and other Works by Depar Apparent Alkyl Transfer and Phenazine Formation via an Aryne Intertment41358Apparent Alkyl Transfer and Phenazine Formation via an Aryne IntermediateDaniel BeckerLoyola University Chicago, dbecke3@luc.eduAndria M. PanagopoulosLoyola University ChicagoDoug SteinmanLoyola University ChicagoAlexandra GoncharenkoLoyola University ChicagoKyle Gearyfollow tỸi?sZẩnầ ucố Apparent Alkyl Transfer and Phenazine Formation via an Aryne Inteniorẵĩworks at: https://ecommons.luc.edu/chemistry_facpubsÒ* Part of the Chemistry CommonsÂtft Rồ¥rirtr'ona/ authorsThis is a pre-publication author mApparent Alkyl Transfer and Phenazine Formation via an Aryne Inte
anuscript of the final, published article.Recommended CitationBecker, Daniel; Panagopoulos, Andria M.; Steinman, Doug, Goncharenko, Alexandra; Geary, LOYOLAffl eCOMMONSLoyola University ChicagoLoyola eCommonsChemistry: Faculty Publications and other WorksFaculty Publications and other Works by Depar Apparent Alkyl Transfer and Phenazine Formation via an Aryne Intenal of Organic Chemistry, 78.8:, 2013. Retrieved from Loyola eCommons, Chemistry: Faculty Publications and Other Works, http://dx.doi.org/10.1021/jo302795wThis Article is brought to you for free and open access by the Faculty Publications and other Works by Department at Loyola eCommons. It has been Apparent Alkyl Transfer and Phenazine Formation via an Aryne Inte accepted for inclusion in Chemistry: Faculty Publications and other Works by an authorized administrator of Loyola eCommons. For more information, plApparent Alkyl Transfer and Phenazine Formation via an Aryne Inte
ease contact ecommons@luc edu.This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 3.0 License. © 2013 AmericaLOYOLAffl eCOMMONSLoyola University ChicagoLoyola eCommonsChemistry: Faculty Publications and other WorksFaculty Publications and other Works by Depar Apparent Alkyl Transfer and Phenazine Formation via an Aryne Inteisman, Elizabeth Spaargaren, and Matthias ZellerThis article is available at Loyola eCommons: https://ecommon5.luc edu/chemistry.facpubs/41Apparent Alkyl Transfer and Phenazine Formation via an Aryne IntermediateAndria M. Panagopoulos.50 Doug Steinman.5 Alexandra Goncharenko.5 Kyle Geary?Carlenc Sch Apparent Alkyl Transfer and Phenazine Formation via an Aryne Inteleisman? Elizabeth spaargarcn? Matthias Zeller.’ and Daniel p. Becker5*'Department of Chemistry, Jjoyola University Chicago, 1032 IV. Sheridan Road. CApparent Alkyl Transfer and Phenazine Formation via an Aryne Inte
hicago, IL 60660. United States. Department of Chemistry, I University Plaza. Youngstown State University, Youngstown, Ohio 44555-3663, United StalesiLOYOLAffl eCOMMONSLoyola University ChicagoLoyola eCommonsChemistry: Faculty Publications and other WorksFaculty Publications and other Works by Depar Apparent Alkyl Transfer and Phenazine Formation via an Aryne Intel derivatives 3a and 3(1 or fluorotriaryl derivatives 3b and 3c with potassium di isopropyl am ide afforded alkyl-shifted phenazine derivatives 5a/5b. rather than the expected 9-membered triaza ơrrAơcyclophane 2a. The phenazine derivatives were isolated in 78-98% yield depending on the halogen and a Apparent Alkyl Transfer and Phenazine Formation via an Aryne Intelkyl group present. In the absence of the halogen (chloro or fluoro), the apparent alkyl shift proceeds more slowly and cannot proceed via. the intermApparent Alkyl Transfer and Phenazine Formation via an Aryne Inte
ediacy of the aryne intermediate.. Mechanistic possibilities include intramolecular nucleophilic attack on an aryne intermediate leading to a zwitteriLOYOLAffl eCOMMONSLoyola University ChicagoLoyola eCommonsChemistry: Faculty Publications and other WorksFaculty Publications and other Works by DeparLOYOLAffl eCOMMONSLoyola University ChicagoLoyola eCommonsChemistry: Faculty Publications and other WorksFaculty Publications and other Works by DeparGọi ngay
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