Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
➤ Gửi thông báo lỗi ⚠️ Báo cáo tài liệu vi phạmNội dung chi tiết: Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
DECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions not copied from any other resources. The literature references have been quoted with clear citation as requested.Thesis authorTran Boi ChauiTÓM TA I LUẬN ẤNLuận án nhảm kháo sát hoạt linh xúc lác của Cu-MOF-74, Cu?(OBA)?(BPY) và MOI -235 cho phân ứng hình thành lien kềl carbon-dị tò. Nội dung của lu Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions ận án được trinh bày thành bốn chương:Chương 1: Tòng quan về Cu-MOF-74. CxuíOBAhCBPY). MOF-235 vã phan ứng hình thành lien kèt carbon-dị lô. Chương 1Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
trinh bày các ưu. nhược diêm của các vật liệu khung cơ kim (MOI's) khi được ứng dụng lâm xúc lác; hoạt lính xúc lác của các vật liệu Xốp. khung hừu cơDECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions vòng benzene. Dồng thòi, trong chương I cùng nêu tóm tắt về phương pháp tống hợp, đặc trưng hóa lý và một sổ các ứng dụng cũa ba loại vật liệu Cu-MOF-74. Cu2(0BAh(BPY), MOF-235.Chương 2: Trinh bày về thực nghiệm và kết quã của phân tích đặc trưng cẩu trúc của Cu-MOF-74, CU2(OBA)2ÍBPY). MOF-235. Các Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions loại vật liệu được tồng hợp bằng phương pháp nhiệt dung mời và được phân lích các đặc trưng hóa lý bang phương pháp nhiễu xạ lia X dạng bột (P-XRD). pApplication of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
hờ hồng ngoại (FT-1R). kính hiên vi điện lữ quét (SEM), kính hiển vi diện tữ truyền qua (TEM), do diện tích bề mặt bằng phương pháp hấp phụ đẳng nhiệtDECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions hóa trực ticp giừa .V-(quinolin-S-yl)bcnzamidcs với alcohols.'phenols. Hoạt tính xúc ĩãc cua MOF-235 cho phan ững oxỵ hóa cộng võng giừa benzyl alcohols và 2-amhiophenols.'2-aminothiophenols. Hoạt tính xúc tác cùa Cuj(OBA)2(BPY) trong phán ứng tòng hợp quinazolines. 4Jf-3,l-benzoxazines. Các phân ún Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions g được kháo sát lính dị thê vã lái sứ dụng xúc lác trong đicu kiện phân ứng.Chương 4: Trinh bày tóm tắt về các kết quá đạt được cùng nhu các đóng gópApplication of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
chính của luận án. dồng thời dề xuất một số hướng nghiên cứu tiếp theo.iiABSTRACTMetal organic frameworks (MOI s) arc a well-known class of materials DECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions ; while compared with conventional heterogeneous catalysts. MOFs have structural and chemical tunability. Metal-organic frameworks based on copper or iron metal sites have been used as catalysts for carbon-hctcroalom bond forming reactions. These copper-based MOT'S or iron-based MOFs arc promising o Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions wing to the utilization of non-prccious and less toxic metal salt species. Herein: Cu-MOF-74. Cu?(OBA)?(BPY), MOF-235 were synthesized by solvothermalApplication of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
method, and characterized by P-XRI), SEM, TEM, TGA, I T-IR. nitrogen physisorption measurements. Catalytic activities of these MOFs were investigatedDECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions des with alcohols'phenols. Besides, the synthesis of some Ar,A-, N.O-, A’.S-heterocyclic compounds was studied via two approaches. One approach was based on the oxidative cyclization reaction between 2-ammophenols/2-aminothiophenols and alcohols catalyzed by MOF-235. The other was a one-pot. two-ste Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions p process which involved the condensation of aldehydes with 2-aminobenzylamincs/2-aminobenzyl alcohols/ 1.2-phenylenediamines in catalyst-free conditiApplication of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
ons, followed by oxidative dehydrogenation of C—N bond catalyzed by Cu_>(OBA)2(BPY). .All the surveyed catalysts were examined for the heterogeneity aDECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions reviously mentioned.iiiACKNOWLEDGMENTThis thesis has been carried out at Ho Chi Minh University of Technology since 2014. It may not be a very long time for someone else, but it will always be the suffering time as well as the best time in my life. I have never ever thought that I could get through Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions this tough time in life. Fortunately, there always are my warmhearted and enthusiastic scientific advisors accompanying with me to my success. The motApplication of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
ivation of them always cheer me up at the right time and help me to go ahead to the final target. I can never give enough my thanks to Prof. Dr. Phan DECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions emaining of my life.It is an absolute misstep if I could not give my grateful thanks to Assoc. Prof. Dr. Pham Thanh Quan. Assoc. Prof. Dr. Le Thi Hong Nhan, Dr. Phan Thi Hoang Anh. All my lecturers are so kindness to boost me up whenever I got troubles to conduct the thesis or even some problems hap Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions pened in personal life.Additionally. I would like to send my great thanks to all friends that I met in the laboratory for their excellent helps duringApplication of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
the period of carrying experiments. I give my sincerely thanks to Ha Quang Hiep. Doan Hoai Son. Duong Ngoc Tan Xuan, To Anh Tuong. Dang Van Hieu. AmoDECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions between me with others.Finally. I would like to express my profound gratitude to my parents and also to my partner for providing me perfect support and encouragement during the entire course even in the hard time of writing this thesis.Tran Boi ChauivTABLE OF CONTENTSTABLE OF CONTENTS.............. Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions ................................................VLIST OF FIGURES.............................................................viiiLIST OF SCHEMES......Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions
.........................................................xiLIST OFTABLES................................................................xiiLIST OF ABBDECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are n Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions HAPTER I. Cu-MOF-74, Cu2(OBA)2BPY, MOF-235 AND CARBON-11 ETEROATOM BOND FORMING REACTIONS............................................21.1.Introduction to metal-organic frameworks................................21.1.1.Possibility of catalytic application of MOFs........................31.1.1.1. Limit Application of cu mof 74, cu2(oba)2(bpy), mof 235 as catalysts for carbon heteroatom bond forming reactions ations of MOFs as catalysts...............................31.1.1.2. The prospects of MOFs as catalysts.............................5DECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are nDECLARATION OF ORIGINALITYI hereby declare that this is my own research study. The research results and conclusions in this thesis are true, and are nGọi ngay
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