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Designed synthsis of novel metal organic frameworks for photocatalyst application

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Nội dung chi tiết: Designed synthsis of novel metal organic frameworks for photocatalyst application

Designed synthsis of novel metal organic frameworks for photocatalyst application

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application AL ƯNIVERSITY-HOCHIMINH CITYBACH KHOA UNB ERSITY HOC HIMINH CITYHA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST AP

PLICATIONMajor subject: TECHNOLOGY FOR ORGANIC COMPLEXESMajor subject code: 62527505Independent Referee 1: Prof Dr. Khoa Cuu NGUYENIndependent Referee Designed synthsis of novel metal organic frameworks for photocatalyst application

2: Assoc. Prof. Dr. Huven Thanh PHAMReferee 1: Assoc. Prof. Dr. Tuan Anh vuReferee 2: Assoc. Prof. Dr. Hoang Thai NGUYENReferee 3: Assoc. Prof. Dr. Q

Designed synthsis of novel metal organic frameworks for photocatalyst application

uan Thanh PHAMSUPERVISORS1. Prof. Dr. Nam Thanh Son PHAN2. Dr. Danh Thanh TONGPROTESTATIONI would like to protest that the research, which will be rep

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application ted to the development progress of science. Any claim and conclusion were cited by the references and documented papers, rhe author recognized that th

e seriousness and authenticity need to be strongly considered.AuthorIla Lac Nguyen1ABSTRACTOver the past two decades, the prominent growth of Metal Or Designed synthsis of novel metal organic frameworks for photocatalyst application

ganic Frameworks (MOFs). a high ordered and porous materials class had been receiving the pay attention by the research community specially. Construct

Designed synthsis of novel metal organic frameworks for photocatalyst application

ing by Secondary Building Units (SBUs) of metal clusters and organic linkers combination that permits the modification of resultant structural modular

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application .. pore size, porosity) to make MOFs address the environment problems as well as the targeted applications such as gas uptake, separation, catalyst, d

rug deliver}', water treatment. In term of MOFs synthesis, the plenteous chemistry of metal and controllability of organic linkers were exploited to m Designed synthsis of novel metal organic frameworks for photocatalyst application

ake the uncountable amount of new MOFs material. In this case, the simple solvothermal reaction or other methods (e.g., hydrothermal, solvent free, sl

Designed synthsis of novel metal organic frameworks for photocatalyst application

ow dispersion) was usually employed to obtain new MOFs. This method for MOFs synthesis can generally predict the obtained structures based on the geom

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application r synthetic approach to designing new MOF materials remains elusive as a result of the trial-and-error nature of crystallization processes, a lack of

control over crystallization, and the regular discoveries of multiple crystalline phase products once the reaction is complete. In MOF chemistry. the Designed synthsis of novel metal organic frameworks for photocatalyst application

building block method, whereby discrete, preassembled metal 0X0 clusters are reacted with well-defined organic linkers, has been utilized to achieve a

Designed synthsis of novel metal organic frameworks for photocatalyst application

greater degree of control over MOF construction. However, the isolation and subsequent usage of many discrete metal 0X0 clusters remains a significan

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application itionally. It IS far from given that the desired MOF structure will be obtained as metal 0X0 building blocks have been observed to rearrange during th

e synthesis Means of overcoming this lack of total synthetic control is to take inspiration from molecular synthesis, in which certain conditions have Designed synthsis of novel metal organic frameworks for photocatalyst application

been discovered to achieve specific end products. In this contribution, we articulate a strategy for making discrete metal clusters in situ that arei

Designed synthsis of novel metal organic frameworks for photocatalyst application

iappropriately functionalized to affect imine condensation reactions, commonly used in the chemistry of covalent organic frameworks (COFs). We find th

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application features of targeted material, termed MOF-901. was fully characterized powder X-ray diffraction and supplemental analyses. As a result of the incorpor

ation of Ti(IV) units. MOF-901 was proven to be photocatalytically active and was applied to the photocatalyzed polymerization of methyl methacrylate Designed synthsis of novel metal organic frameworks for photocatalyst application

(MMA).For further investigation, the photocatalysis properties of MOF which is isorclicular to MOF-901 structure, MOF-902 was successfully synthesized

Designed synthsis of novel metal organic frameworks for photocatalyst application

by enlarging the linking unit, and applied to the application of polymerization reaction with these kinds of monomer: methylmethacrylate (MMA), benzy

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application e of polyMMA which IS produced by MOF-901 catalyst, and the poly dispersity index of polyMMA produced by MOF-902 catalyst IS lower than MOF-901 (1.27

compared to 1.60).Moreover, we have successfully synthesized three novel MOFs termed MOF-903(Fe). MOF-904(Fe), and VNU-18(Cu) based on triangular Iron Designed synthsis of novel metal organic frameworks for photocatalyst application

(III) cluster and extraordinary three discrete Cu(II) building units, respectively. These materials were frill characterized by the powder X-ray diff

Designed synthsis of novel metal organic frameworks for photocatalyst application

raction, single crystal X-ray diffraction analysis, thcrmogravimclric analysis, gas adsorption study. MOF-904 and VNU-1S show the permanent porosity w

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

Designed synthsis of novel metal organic frameworks for photocatalyst application e.illACKNOWLEDGEMENTSOn the way to achieve the professional skills and knowledge in the research. I had turned to different vicissitude. Fortunately.

I was always received the support and encouragement by many people as well as the great results from my efforts. In this context. I would like to give Designed synthsis of novel metal organic frameworks for photocatalyst application

my honest acknowledgements to all.

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

HA LAC NGUYENDESIGNED SYNTHESIS OF NOVEL METAL-ORGANIC FRAMEWORKS FOR PHOTOCATALYST APPLICATIONDOCTORAL DISSERTATIONHOCHIMINH CITY 2017VIETNAM NATIONA

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