Introduction to quantum mechanics; with applications to chemistry
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Introduction to quantum mechanics; with applications to chemistry
INTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications to Introduction to quantum mechanics; with applications to chemistry ChemistryBYLINUS PAULING, Ph.D., Sc.D.Professor of Chemistry, California Institute of TechnologyANDE. BRIGHT WILSON, Jr., Ph.D.Associate Professor of Chemistry, Harvard UniversityMcGRAW-HILL BOOK COMPANY, Inc. NEW YORK AND LONDON 1935Copyright, 1935, BY THE McGraw-Hill Book Company, Inc.PRINTED IN Introduction to quantum mechanics; with applications to chemistry THK UNITED STATES OK AMERICAAll rights reserved. This book, or parts thereof, may not be reproduced in any form without permission of the publishers.XIntroduction to quantum mechanics; with applications to chemistry
VTTTUP, MAPLE PRESS COMPANY. YORK, PA.PREFACEIn writing this book we have attempted to produce a textbook of practical quantum mechanics for the chemiINTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications to Introduction to quantum mechanics; with applications to chemistry mechanics, nor even to present a thorough survey of the subject. We hope that it does give a lucid and easily understandable introduction to a limited portion of quantum-mechanical theory; namely, that portion usually suggested by the name “wave mechanics,” consisting of the discussion of the Schro Introduction to quantum mechanics; with applications to chemistry dinger wave equation and the problems which can be treated by means of it. The effort has been made to provide for the reader a means of equipping himIntroduction to quantum mechanics; with applications to chemistry
self with a practical grasp of tills subject, so that he can apply quantum mechanics to most of the chemical and physical problems which may confront INTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications to Introduction to quantum mechanics; with applications to chemistry the subject because of its chemical applications. We have assumed on the part of the reader, in addition to elementary mathematics through the calculus, only some knowledge of complex quantities, ordinary differential equations, and the technique of partial differentiation. It may be desirable that Introduction to quantum mechanics; with applications to chemistry a book written for the reader not adept at mathematics be richer in equations than one intended for the mathematician; for the mathematician can follIntroduction to quantum mechanics; with applications to chemistry
ow a sketchy derivation with ease, whereas ư the loss adept reader is to be led safely through the usually straightforward but sometimes rather compliINTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications to Introduction to quantum mechanics; with applications to chemistry erstanding of the subject without a thorough knowledge of the mathematical methods involved and the results of their application cannot be obtained. The student not thoroughly trained in the theory of partial differential equations and orthogonal functions mustivPREFACElearn something of these subje Introduction to quantum mechanics; with applications to chemistry cts as he studies quantum mechanics. In order that he may do so, and that he may follow the discussions given without danger of being deflected from tIntroduction to quantum mechanics; with applications to chemistry
he course of the argument by inability to carry through some minor step, we have avoided the temptation to condense the various discussions into shortINTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications to Introduction to quantum mechanics; with applications to chemistry ve equation and its physical interpretation on a postulatory basis, and have then given in great detail the solution of the wave equation for important systems (harmonic oscillator, hydrogen atom) and the discussion of the wave functions and their properties, omitting none of the mathematical stops Introduction to quantum mechanics; with applications to chemistry except the mostA similarly detailed treatment has been given in the discussion 0*1 pertirfuafaon‘òíeor^, the variation method, the structure of simpleIntroduction to quantum mechanics; with applications to chemistry
molecules, and, in general, ÌÍ1 •'. important section of the book.In order to limit the size of the book, we have omitted from discussion such advancINTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications to Introduction to quantum mechanics; with applications to chemistry ntization of the electromagnetic field, etc. We have also omitted several subjects which are ordinarily considered as part of elementary quantum mechanics, but which are of minor importance to the chemist, such as the Zeeman effect and magnetic interactions in general, the dispersion of light and al Introduction to quantum mechanics; with applications to chemistry lied phenomena, and most of the theory of aperiodic processes.The authors are severally indebted to Professor A. Sommerfeld and Professors E. u. CondoIntroduction to quantum mechanics; with applications to chemistry
n and H. p. Robertson for their own introduction to quantum mechanics. The constant advice of Professor R. c. Tolman is gratefully acknowledged, as weINTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications to Introduction to quantum mechanics; with applications to chemistry am Wilson, and Mrs. Ava Helen Pauliụg.Linus Pauling.E. Bright Wilson, Jr.pA.HAnv.MA 1 .*1.1»CONTENTSINTROOUCnON TOQUantumIMECHANICSWith Apokorjons ro Cherrist f yLinus Poulng ond E Dí-ựY Wilson. JcINTRODUCTIONTO QUANTUM MECHANICSWith Applications toGọi ngay
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