Organic reactions v1
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Organic reactions v1
Organic ReactionsVOLUME 1EDITORIAL BOARDRoger Adams, Editor-in-ChiefWerner E. BachmannJohn R. JohnsonLouis F. FieserH. R. SnyderASSOCIATE EDITORSA. H. Organic reactions v1 . BlattCharles R. HauserF. F. BlickeMarlin T. LefflerNathan L. DrakeElmore L. MartinReynold c. FusonRalph L. ShrinerLee Irvin SmithNEW YORKJOHN WILEY & SONS, INC.London: chapman & HALL, Limited'942Copyright, 1942 BY Roger AdamsAU Rights ReservedThis took or any part thereof must not be reproduced in Organic reactions v1 any form without the written permission of the publisher.PRINTED IN THE UNITED STATES OF AMERICAPREFACEIn the course of nearly every program of reseaOrganic reactions v1
rch in organic chemistry the investigator finds it necessary to use several of the better-known synthetic reactions. To discover the optimum conditionOrganic ReactionsVOLUME 1EDITORIAL BOARDRoger Adams, Editor-in-ChiefWerner E. BachmannJohn R. JohnsonLouis F. FieserH. R. SnyderASSOCIATE EDITORSA. H. Organic reactions v1 iterature; even then a series of experiments may be necessary. When the results of the investigation are published, the synthesis, which may have required months of work, is usually described without comment. The background of knowledge and experience gained in the literature search and experimentat Organic reactions v1 ion is thus lost to those who subsequently have occasion to apply the general method. The student of preparative organic chemistry faces similar diffiOrganic reactions v1
culties. The textbooks and laboratory manuals furnish numerous examples of the application of various syntheses, but only rarely do they convey an accOrganic ReactionsVOLUME 1EDITORIAL BOARDRoger Adams, Editor-in-ChiefWerner E. BachmannJohn R. JohnsonLouis F. FieserH. R. SnyderASSOCIATE EDITORSA. H. Organic reactions v1 iling critical discussions of the more important reactions thus was evolved. Volume I of Organic Reactions is a collection of twelve chapters, each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The Organic reactions v1 subjects are presented from the preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structureOrganic reactions v1
, and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the meOrganic ReactionsVOLUME 1EDITORIAL BOARDRoger Adams, Editor-in-ChiefWerner E. BachmannJohn R. JohnsonLouis F. FieserH. R. SnyderASSOCIATE EDITORSA. H. Organic reactions v1 een subjected to careful testing in two or more laboratories. When all known examples of the reaction are not mentioned in the text, tables are given to list compounds which have been prepared by or subjected to the reaction. Every effort has been made to include in the tables all such compounds and Organic reactions v1 references; however, because of the very nature of the reactions discussed and their frequent use as one of the several steps of syntheses in which nOrganic reactions v1
ot all of the intermediates have been isolated, some instances may well have been missed. Nevertheless, theVvi•PREFACEinvestigator will be able to useOrganic ReactionsVOLUME 1EDITORIAL BOARDRoger Adams, Editor-in-ChiefWerner E. BachmannJohn R. JohnsonLouis F. FieserH. R. SnyderASSOCIATE EDITORSA. H. Organic reactions v1 ment of the material in the chapters and the entries in the tables, users of the book will be able to find information desired by reference to the table of contents of the appropriate chapter. In the interest of economy the entries in the index have been kept to a minimum, and, in particular, the co Organic reactions v1 mpounds listed in the tables are not repeated in the index.The success of this publication, which will appear periodically in volumes of about twelveOrganic reactions v1
chapters, depends upon the cooperation of organic chemists and the ừ willingness to devote time and effort to the preparation of the chapters. They haOrganic ReactionsVOLUME 1EDITORIAL BOARDRoger Adams, Editor-in-ChiefWerner E. BachmannJohn R. JohnsonLouis F. FieserH. R. SnyderASSOCIATE EDITORSA. H. Organic reactions v1 nued interest and their suggestions for improvements in Organic Reactions.CONTENTSCHAPTERPAGE1The Reformatsky Reaction—Ralph L Shrzner12The Arndt-Eistert Synthesis—w. E. Bachmann and w s Struve 383.Chloromethylation of Aromatic Compounds—Reynold c Fuson andc. H. McKeever63 Organic reactions v1 Organic ReactionsVOLUME 1EDITORIAL BOARDRoger Adams, Editor-in-ChiefWerner E. BachmannJohn R. JohnsonLouis F. FieserH. R. SnyderASSOCIATE EDITORSA. H.Gọi ngay
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