Progress in physical organic chemistry, volume 4
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Progress in physical organic chemistry, volume 4
Progress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of Chemistry Progress in physical organic chemistry, volume 4 y University of California, Berkeley, CaliforniaROBERT w. TAFT, Department of Chemistry University of California, ĩrvìne, California1967INTERSCIENCE PUBLISHERSa division of John Wiley if Sons • iNeiv York • London • Sydneywww.pdfgrip.comCopyright © 1ÍMỈ7 by John Wiley and Sons, Inc.AU rights reserve Progress in physical organic chemistry, volume 4 dLibrary of Congress Catalog Card Number 63-19364PRINTED IN THE UNITED STATES OF AMERICAwww.pdfgrip.comIntroduction to the SeriesPhysical organic chemProgress in physical organic chemistry, volume 4
istry is a relatively modern field with deep roots in chemistry. The subject is concerned with investigations of organic chemistry by quantitative andProgress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of Chemistry Progress in physical organic chemistry, volume 4 of chemical endeavor. Further, the potential for new developments resulting from this union appears to be still greater. A closening of ties with all aspects of molecular structure and spectroscopy is clearly anticipated. The field provides the proving ground for the development of basic tools for Progress in physical organic chemistry, volume 4 investigations in the areas of molecular biology and biophysics. The subject has an inherent association with phenomena in the condensed phase and theProgress in physical organic chemistry, volume 4
reby with the theories of this state of matter.The chief directions of the field are: (a) the effects of structure and environment on reaction rates aProgress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of Chemistry Progress in physical organic chemistry, volume 4 , of course, much of chemistry lies within these confines. The dominant theme that characterizes this field is the emphasis on interpretation and understanding which permits the effective practice of organic chemistry. The field gains its momentum from the application of basic theories and methods o Progress in physical organic chemistry, volume 4 f physical chemistry to the broad areas of knowledge of organic reactions and organic structural theory. The nearly inexhaustible diversity of organicProgress in physical organic chemistry, volume 4
structures permits detailed and systematic investigations which have no peer. The reactions of complex natural products have contributed to the develProgress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of Chemistry Progress in physical organic chemistry, volume 4 natural products.Fundamental advances are offered by the knowledge of energy states and their electronic distributions in organic compounds and the relationship of these to reaction mechanisms. The development, for example, of even an empirical and approximate general schemeVwww.pdfgrip.comviINTRODU Progress in physical organic chemistry, volume 4 CTION TO THE SERIESfor the estimation of activation energies would indeed l>e most notable.The complexity of even the simplest organic compounds in teProgress in physical organic chemistry, volume 4
rms of physical theory well endows the field of physical organic chemistry with the frustrations of approximations. The quantitative correlations emplProgress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of Chemistry Progress in physical organic chemistry, volume 4 ommon procedures have involved the application of approximate theories to approximate models. Critical assessment of the scope and limitations of these approximate applications of theory leads to further development and understanding.Although he may wish to be a disclaimer, the physical organic chem Progress in physical organic chemistry, volume 4 ist attempts to compensate his lack of physical rigor by the vigor of his efforts. There has indeed been recently a great outpouring of work in this fProgress in physical organic chemistry, volume 4
ield. We believe that a forum for exchange of views and for critical and authoritative reviews of topics is an essential need of this field. It is ourProgress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of Chemistry Progress in physical organic chemistry, volume 4 rly presentations of our series will correspond to that of the several prototypes, e.g., Advances in- Enzymology, Advances in Chemical Physics, and Progress in Inorganic Chemistry.We have encouraged the authors to review topics in a style that is not only somewhat more speculative in character but w Progress in physical organic chemistry, volume 4 hich is also more detailed than presentations normally found in textbooks. Appropriate to this quantitative aspect of organic chemistry, authors haveProgress in physical organic chemistry, volume 4
also been encouraged in the citation of numerical data. It is intended that these volumes will find wide use among graduate students as well as practiProgress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of Chemistry Progress in physical organic chemistry, volume 4 is in each chapter is the personal ideas of the author. We wish to express our gratitude to the authors for the excellence of their individual presentations.We greatly welcome comments and suggestions on any aspect, of these volumes.Andrew Streitwieser, Jr. Progress in physical organic chemistry, volume 4 Progress inORGANIC CHEMISTRYVOLUME 4www.pdfgrip.comProgress inPHYSICALORGANICCHEMISTRYVOLUME 4Ed HoraANDREW STREITWIESER, JR., Department of ChemistryGọi ngay
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