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product EO by shell

A Simulation Model of a reactor for Ethylene Oxide productionbyHanna PerzonDepartment of Chemical EngineeringLund University42156Supervisor: Assoc. Pr

product EO by shell rof. C hristian HultebergCo-supervisor: Andreas FriborgExaminer: Assoc. Prof. Mats GalbePostal address p o. Box 124SE-221 00 Lund, Sweden Web addressW

WW chemeng Ith seVisiting addressGetingevagen 60Telephone+46 46-222 82 85+46 46-222 00 00Telefax+46 46-222 45 26PrefaceTills thesis has been done at t product EO by shell

he chemical department of Chemical Engineering at Lund’s University together with AkzoNobel. All the work has been performed at the process department

product EO by shell

at AkzoNobel in Stenungsund.I would like to thank AkzoNobel and especially Hendrik van Dam. the manager of the process department how gave me the opp

A Simulation Model of a reactor for Ethylene Oxide productionbyHanna PerzonDepartment of Chemical EngineeringLund University42156Supervisor: Assoc. Pr

product EO by shell ng this time.Special thanks I want to give to my Co-Supervisor. Andreas Friborg at Hansson & Friborg Process Engineering. Andreas has been a great sup

port by contributing with his great knowledge, infinite patience and kindness.I would also like to thank my supervisor at Lund’s University. Christian product EO by shell

Hulteberg for his support during this time.Last. I would like to thank my family and friends for your support and patient during this time.Hanna Perz

product EO by shell

on42156LundAbstractThis thesis has been performed in the ethylene oxide plant at Akzo Nobel in Stenungsund. Ethylene oxide is an important ethylene ba

A Simulation Model of a reactor for Ethylene Oxide productionbyHanna PerzonDepartment of Chemical EngineeringLund University42156Supervisor: Assoc. Pr

product EO by shell ne’s.In the production of ethylene oxide, ethylene and oxygen reacts over a silver catalyst surface. Mainly two reactions occur, partial oxidation of

ethylene to ethylene oxide and total oxidation of ethylene to carbon dioxide and water. The largest cost in production of ethylene oxide is ethylene t product EO by shell

herefore it’s important to optimize the selectivity towards ethylene oxide and thus reduce the consumption of ethylene.Tire aim with this thesis was t

product EO by shell

o create a simulation model of the reactor using Aspen Plus' that correlates with reality. This model is then going to be a tool for future investigat

A Simulation Model of a reactor for Ethylene Oxide productionbyHanna PerzonDepartment of Chemical EngineeringLund University42156Supervisor: Assoc. Pr

product EO by shell nism in the reactor.Part of this project was to find a thermodynamic model that correlate with the system. Based on the literature study an equation o

f state model. Peng-Robinson or Soave-Redlich-Kwong was the best choice. Both models were tested and they gave similar results. In this simulation Soa product EO by shell

ve-Redlich-Kwong is used. The reason for that is that Soave-Redlich-Kwong is developed to function well together with water which condenses in the hea

product EO by shell

t exchangers after the reactor (simulation model will incorporate more process equipment in future studies).Multiple studies have been done to discove

A Simulation Model of a reactor for Ethylene Oxide productionbyHanna PerzonDepartment of Chemical EngineeringLund University42156Supervisor: Assoc. Pr

product EO by shell hanisms described. It is agreed that silver can adsorb oxygen in a number of ways and that this phenomenon is the basis of silver’s efficiency in cata

lyzing the oxidation of ethylene to ethylene oxide. product EO by shell

A Simulation Model of a reactor for Ethylene Oxide productionbyHanna PerzonDepartment of Chemical EngineeringLund University42156Supervisor: Assoc. Pr

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