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Synthesis of cobalt and iron based metal organic frameworks and their applications

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Nội dung chi tiết: Synthesis of cobalt and iron based metal organic frameworks and their applications

Synthesis of cobalt and iron based metal organic frameworks and their applications

VIETNAM NATIONAL UNIVERSITY - HO CHI MINH CITYHO CHI MINH CITY UNIX ERSITY OF TECHNOLOGYTU NGOC THACHSYNTHESIS OF COBALT AND IRON-BASED METAL-ORGANICF

Synthesis of cobalt and iron based metal organic frameworks and their applications FRAMEWORKS AND THEIR APPLICATIONSPhD THESISHO CHI MINH CITY. 2016VIETNAM NATIONAL UNIVERSITY - HO CHI MINH CITYHO ( Ill MINH CH Y UNIVERSITY OF TECHNO

LOGYTƯNGOC THACHSYNTHESIS OF COBAI ;r AND IRON-BASED METAL-ORGANIC FRAMEWORKS AND THEIR .APPLICATIONSFaculty: Chemical Engineering, Division of Organi Synthesis of cobalt and iron based metal organic frameworks and their applications

c Chemical EngineeringDivision code: 62527505Independent Reviewer 1: Prof. Dr. DINH Thi NeoIndependent Reviewer 2: Assoc. Prof. Dr. VƯ Anh TuanReviewe

Synthesis of cobalt and iron based metal organic frameworks and their applications

r 1: Assoc. Prof. Dr. NGUYEN Thi Phuong PhongReviewer 2: Assoc. Prof. Dr. NGUYEN Cuu KhoaReviewer 3: Assoc. Prof. Dr. LE Van ChangScientific Advisor:

VIETNAM NATIONAL UNIVERSITY - HO CHI MINH CITYHO CHI MINH CITY UNIX ERSITY OF TECHNOLOGYTU NGOC THACHSYNTHESIS OF COBALT AND IRON-BASED METAL-ORGANICF

Synthesis of cobalt and iron based metal organic frameworks and their applications esis are honest, and not copied from any source in any shape or form. The reference sources cited were made and recorded reference sources according t

o specifications.Author of the ThesisTư NGOC THACHTU N. THACHABSTRACTThe synthesis, structural identification of four novel cobalt and iron-based meta Synthesis of cobalt and iron based metal organic frameworks and their applications

l-organic frameworks (MOFs). named VNU-10 (cobalt-based MOF), VNƯ-15 (iron-based MOF, VNU = Vietnam National University), Fe-NH.'-BDC and Fe-BTC have

Synthesis of cobalt and iron based metal organic frameworks and their applications

been done by single crystal x-ray diffraction (SC-XRD). Full characterization and applications of VNƯ-10, VNU-15 were undertaken and preliminary chara

VIETNAM NATIONAL UNIVERSITY - HO CHI MINH CITYHO CHI MINH CITY UNIX ERSITY OF TECHNOLOGYTU NGOC THACHSYNTHESIS OF COBALT AND IRON-BASED METAL-ORGANICF

Synthesis of cobalt and iron based metal organic frameworks and their applications ptional catalytic activity toward the direct amination of bezoxazoles via CH/N-H couplings while a previously reported topological isomer. C’O2(BDCh(D

ABCO)sqi displayed poor activity under testing condition. Leaching tests indicated that homogeneous catalysis via leached active cobalt species is unl Synthesis of cobalt and iron based metal organic frameworks and their applications

ikely. Furthermore, the VNU-10 catalyst was facilely isolated from the reaction mixture and reused several times without degradation of the catalytic

Synthesis of cobalt and iron based metal organic frameworks and their applications

reactivity.VNU-15 with integrated sulphate ligands accompanied by hydrogen-bonded dimethyl ammonium ions that lined the pore channels, the proton cond

VIETNAM NATIONAL UNIVERSITY - HO CHI MINH CITYHO CHI MINH CITY UNIX ERSITY OF TECHNOLOGYTU NGOC THACHSYNTHESIS OF COBALT AND IRON-BASED METAL-ORGANICF

Synthesis of cobalt and iron based metal organic frameworks and their applications ditions (1.0 X IO’2 s cm1 at 60% RH and 80 °C) and on the order of a magnitude higher than that observed in several of the highest performing MOFs rep

orted, albeit these materials’ proton conductivity properties were reported with high working relative humidity (RH > 90%). Remarkably, the ultrahigh Synthesis of cobalt and iron based metal organic frameworks and their applications

proton conductivity of VNU-15 was maintained under these conditions, without any appreciable loss, for 40 hours.iiTU N. THACHACKNOWLEGDMENTI would lik

Synthesis of cobalt and iron based metal organic frameworks and their applications

e to give acknowledgement toMy Adviser, Prof. Nam Son Thanh Phan who gave valuable research directions and guided me to achieve the final scientific g

VIETNAM NATIONAL UNIVERSITY - HO CHI MINH CITYHO CHI MINH CITY UNIX ERSITY OF TECHNOLOGYTU NGOC THACHSYNTHESIS OF COBALT AND IRON-BASED METAL-ORGANICF

VIETNAM NATIONAL UNIVERSITY - HO CHI MINH CITYHO CHI MINH CITY UNIX ERSITY OF TECHNOLOGYTU NGOC THACHSYNTHESIS OF COBALT AND IRON-BASED METAL-ORGANICF

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